阻塞(统计)
磁化
磁铁
单分子磁体
材料科学
凝聚态物理
磁场
物理
计算机科学
计算机网络
量子力学
作者
Veacheslav Vieru,Silvia Gómez‐Coca,Eliseo Ruíz,Liviu F. Chibotaru
标识
DOI:10.1002/anie.202303146
摘要
Abstract The synthesis of single‐molecule magnets (SMMs), magnetic complexes capable of retaining magnetization blocking for a long time at elevated temperatures, has been a major concern for magnetochemists over the last three decades. In this review, we describe basic SMMs and the different approaches that allow high magnetization‐blocking temperatures to be reached. We focus on the basic factors affecting magnetization blocking, magnetic axiality and the height of the blocking barrier, which can be used to group different families of complexes in terms of their SMM efficiency. Finally, we discuss several practical routes for the design of mono‐ and polynuclear complexes that could be applied in memory devices.
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