阳极
多孔性
材料科学
电化学
热解
碳纤维
钠
化学工程
离子
储能
生物量(生态学)
电极
复合材料
化学
冶金
有机化学
复合数
功率(物理)
物理
物理化学
工程类
海洋学
量子力学
地质学
作者
Uldana Kydyrbayeva,Yelnury Baltash,Orynbassar Mukhan,Arailym Nurpeissova,Sung‐Soo Kim,Zhumabay Bakenov,Aliya Mukanova
标识
DOI:10.1016/j.est.2024.112629
摘要
Biomass-derived hard carbon (HC) has attracted much attention as a promising electrode material for sodium-ion batteries (SIBs) due to its unique properties such as high porosity, large surface area and adjustable pore size distribution. This work presents the results of electrochemical studies of HC derived from buckwheat seeds. The HCs were preoxidized at 300 °C and synthesized using a pyrolysis method in the range 600–1400 °C. It was found that the electrochemical characteristics of the HC anodes are strongly dependent on the morphology and structure. Furthermore, the positive effect of preoxidation on the porosity of HC was confirmed. Although all buckwheat-derived HC-based anodes showed stable cyclability over 100 cycles with CE of approximately 97–98 %, the preoxidized HCs pyrolyzed at 1400 °C achieved the highest reversible capacity of 330.23 mAh g−1 with excellent stability. Additional study using "single particle" measurement of HC1400 and HCox1400 showed that the preoxidation may significantly contribute to the improvement of the mass transfer.
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