Scalable Synthesis of Tavorite LiFeSO4F and NaFeSO4F Cathode Materials

Angewandte Chemie International EditionVolume 49, Issue 46 p. 8738-8742 Communication Scalable Synthesis of Tavorite LiFeSO4F and NaFeSO4F Cathode Materials† Rajesh Tripathi, Rajesh Tripathi Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo Ontario N2L 3G1 (Canada), Fax: (+1) 519-746-0435Search for more papers by this authorT. N. Ramesh, T. N. Ramesh Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo Ontario N2L 3G1 (Canada), Fax: (+1) 519-746-0435Search for more papers by this authorBrian L. Ellis, Brian L. Ellis Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo Ontario N2L 3G1 (Canada), Fax: (+1) 519-746-0435Search for more papers by this authorProf. Linda F. Nazar, Prof. Linda F. Nazar [email protected] Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo Ontario N2L 3G1 (Canada), Fax: (+1) 519-746-0435Search for more papers by this author Rajesh Tripathi, Rajesh Tripathi Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo Ontario N2L 3G1 (Canada), Fax: (+1) 519-746-0435Search for more papers by this authorT. N. Ramesh, T. N. Ramesh Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo Ontario N2L 3G1 (Canada), Fax: (+1) 519-746-0435Search for more papers by this authorBrian L. Ellis, Brian L. Ellis Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo Ontario N2L 3G1 (Canada), Fax: (+1) 519-746-0435Search for more papers by this authorProf. Linda F. Nazar, Prof. Linda F. Nazar [email protected] Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo Ontario N2L 3G1 (Canada), Fax: (+1) 519-746-0435Search for more papers by this author First published: 12 October 2010 https://doi.org/10.1002/anie.201003743Citations: 165 † This work was carried out with the financial support of the Canadian Natural Sciences and Engineering Council through their Discovery and Canada Research Chair programs. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Single-phase tavorite, LiFeSO4F, is crystallized in tetraethylene glycol at 220 °C to give an electrochemically highly active material. This route obviates the need for expensive ionic liquids and can be extended to the synthesis of NaFeSO4F, whose structure solution, along with that of the parent framework FeSO4F, provides understanding of ion mobility. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201003743_sm_miscellaneous_information.pdf389.1 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume49, Issue46November 8, 2010Pages 8738-8742 RelatedInformation