佩多:嘘
材料科学
太阳能电池
化学工程
薄脆饼
无定形固体
能量转换效率
纳米技术
混合太阳能电池
拉曼光谱
纳米结构
聚合物太阳能电池
光电子学
光学
化学
有机化学
图层(电子)
物理
工程类
作者
Natsumi Ikeda,Tomoyuki Koganezawa,Daisuke Kajiya,Ken‐ichi Saitow
标识
DOI:10.1021/acs.jpcc.6b07101
摘要
A hybrid solar cell composed of a crystalline semiconductor and polymer film has attracted much attention due to numerous advantages, such as high mobility, long lifetime, and the aqueous solution processing. Recently, the power conversion efficiency (PCE) of the hybrid solar cell of silicon (Si) wafer and poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is reported to be higher than that of a commercial amorphous Si solar cell. Here in the Si/PEDOT:PSS hybrid solar cell was prepared using dimethyl sulfoxide (DMSO) as an additive to the PEDOT:PSS solution. The PCE was increased up to 10-fold by the addition of DMSO at a concentration of 5 wt%. Results from grazing-incidence X-ray diffraction, atomic force microscopy, and Raman spectroscopy indicated the 10-fold enhancement was controlled by the nanostructure of the PEDOT:PSS film. The enhanced performance was attributed to (i) an increase of π–π stacking, (ii) shortened distances between π–π planes, (iii) an increase in the quinoid structure of PEDOT, and (iv) reduced PEDOT:PSS particle size. The PCE was also enhanced by a transparent cathode of colloidal Ag nanowires and through the use of a vacuum-free process for preparation of the PEDOT:PSS film.
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