Mechanochemical Synthesis of Cocrystal: From Mechanism to Application

共晶 机械化学 合成子 晶体工程 纳米技术 超分子化学 材料科学 化学 有机化学 晶体结构 分子 氢键
作者
Yuntian Xiao,Chuanhua Wu,Xingchen Hu,Kui Chen,Luguang Qi,Pingping Cui,Ling Zhou,Qiuxiang Yin
出处
期刊:Crystal Growth & Design [American Chemical Society]
卷期号:23 (6): 4680-4700 被引量:2
标识
DOI:10.1021/acs.cgd.3c00183
摘要

Cocrystal engineering is gaining interest across various disciplines since it can effectively tune the properties of solid substances via noncovalent synthesis by introducing new components into the lattice. Mechanochemistry is without a doubt the most valuable tool for the research of cocrystals, which combines the pursuit of efficient and sustainable process pathways with the exploration of supramolecular synthons that cannot be discovered using solution methods. In this review, concerning the significance of the mechanochemical synthesis of cocrystals, we begin by outlining the strategies for mechanochemical preparation of cocrystals. We then elaborate on the theoretical mechanisms of the mechanochemically induced formation of cocrystals and their polymorphs. On this foundation, several cross-fields in which mechanochemistry enhances the application value of cocrystal engineering are shown to overcome existing limitations, which are difficult or impossible to access using conventional solution methods. More importantly, we demonstrate that the introduction of new methods, such as cultivating single crystals from melt microdroplets, and new techniques, such as microelectron diffraction (Micro-ED), has harmoniously united the fields of cocrystal engineering and mechanochemistry. Finally, a brief conclusion and outlook are presented, including current challenges and future opportunities for the cooperation of mechanochemistry and cocrystal engineering.
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