Efficient Gold Recovery from Cyanide Solution Using Magnetic Activated Carbon

活性炭 吸附 材料科学 碳纤维 化学工程 氰化物 解吸 比表面积 磁性 纳米技术 无机化学 催化作用 有机化学 复合材料 化学 冶金 物理 量子力学 复合数 工程类
作者
Jinsong Xia,Harshit Mahandra,Ahmad Ghahreman
出处
期刊:ACS Applied Materials & Interfaces [American Chemical Society]
卷期号:13 (40): 47642-47649 被引量:19
标识
DOI:10.1021/acsami.1c13920
摘要

Activated carbon has been used for gold recovery in the gold mining industry commercially for decades. The high specific surface area and porosity, good affinity to aurocyanide ions, and abundant resources make activated carbon an efficient and economical material for the adsorption of aurocyanide. However, the separation of activated carbon from the slurry is usually a challenge, and the adsorption rate of activated carbon is limited by the coarse particle size. Herein, a simple and sustainable way to recover gold from cyanide solution using magnetic activated carbon synthesized via a solvothermal method has been developed. The synthesized magnetic activated carbon possesses good magnetism (44.57 emu/g) and specific surface area equal to 249.7 m2/g. The magnetic activated carbon showed 99.1% recovery efficiency of gold from 10 mg/L solution within 5 h, which is much faster compared to the commercial granular activated carbon, and the magnetic activated carbon can be easily separated from the solution with an external magnet. The adsorption ability of this magnetic activated carbon has been tested under different conditions in the cyanide solution, the adsorption isotherm and kinetics are also investigated. The magnetic activated carbon was also recycled in the adsorption–desorption tests and showed good reusability.

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