化学
氢氧化物
催化作用
环加成
铜
炔烃
共沉淀
浸出(土壤学)
点击化学
多相催化
无机化学
核化学
高分子化学
有机化学
土壤水分
土壤科学
环境科学
作者
Noura Aflak,Lekbira El Mersly,Hicham Ben El Ayouchia,Salah Rafqah,Hafid Anane,Miguel Julve,Salah‐Eddine Stiriba
标识
DOI:10.1080/00958972.2022.2105701
摘要
A new Cu3Al-layered double hydroxide (LDH) compound that contains Cu2+ and Al3+ in a 3:1 copper to aluminum molar ratio was synthesized by a coprecipitation method at constant pH and characterized by various methods. Cu3Al-LDH was efficiently used as a catalyst for the regioselective click of 1,4-disubstituted-1,2,3-triazoles by [3 + 2] cycloaddition of several azides and alkynes in water under ambient conditions. The investigated heterogeneous Cu3Al-LDH catalyst was used in lower copper catalyst loading in absence of any additive reducing agent, showing good stability in terms of copper species leaching as well as reusability associated to the loss of the layered structure to some extent during the process of filtration-dehydration.
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