Propane wet reforming over PtSn nanoparticles on γ-Al2O3 for acetone synthesis

Abstract Acetone serves as an important solvent and building block for the chemical industry, but the current industrial synthesis of acetone is generally accompanied by the energy-intensive and costly cumene process used for phenol production. Here we propose a sustainable route for acetone synthesis via propane wet reforming at a moderate temperature of 350 o C with the use of platinum-tin nanoparticles supported on γ-aluminium oxide (PtSn/γ-Al 2 O 3 ) as catalyst. We achieve an acetone productivity of 858.4 μmol/g with a selectivity of 57.8% among all carbon-based products and 99.3% among all liquid products. Detailed spectroscopic and controlled experiments reveal that the acetone is formed through a tandem catalytic process involving propene and isopropanol as intermediates. We also demonstrate facile ketone synthesis via wet reforming with the use of different alkanes ( e.g ., n-butane, n-pentane, n-hexane, n-heptane, and n-octane) as substrates, proving the wide applicability of this strategy.