Recovery and utilization of phosphorus from fruit and vegetable wastewater

吸附 废水 磷酸盐 富营养化 化学 朗缪尔吸附模型 热解 污水处理 制浆造纸工业 营养物 环境工程 环境科学 有机化学 工程类
作者
Yu Qin,Huili Li,Shuanglong Ma,Kai Li,Xiaohan Zhang,Deyin Hou,Xiaoxu Zheng,Cong Wang,Ping Lyu,Shengjun Xu,Wei Zhang
出处
期刊:Scientific Reports [Springer Nature]
卷期号:12 (1) 被引量:3
标识
DOI:10.1038/s41598-021-04430-1
摘要

Excessive discharge of phosphorus into the water bodies is the key factor to cause eutrophication. The fruit and vegetable wastewater contains large amounts of phosphorus, and it may be directly discharged into water bodies, which has a great burden on the municipal sewage pipe network. Therefore, coagulation was used to remove phosphorus, recovered the phosphorus from the wastewater into the precipitate, and then the precipitate was pyrolyzed as an efficient adsorbent for phosphate removal. By comparing the adsorption effects of adsorbents (XT-300, XT-400, and XT-500) with pyrolysis temperatures of 300 °C, 400 °C, and 500 °C on phosphate in actual phosphorus-containing wastewater and simulated phosphorus-containing wastewater at different adsorbent dosage (4 g/L, 7 g/L, and 10 g/L), it was found that XT-300 had the best performance of adsorption, and the adsorption of phosphate was endothermic and obeyed the Langmuir isotherms and Elovich kinetics. The influence of pH, coexisting anions, and the structure of XT-300 revealed that the removal of phosphate was associated with electrostatic attraction, pore filling, but could not be determined whether it was related to surface precipitation. This study provides a way and method for the recovery and utilization of phosphorus in fruit and vegetable wastewater and proves that the synthetic adsorbent was an efficient phosphorus adsorbent. In the long term, we can try to use the adsorbent after phosphorus adsorption to promote plant growth in agricultural systems.
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