Novel mushroom-like cotton-based evaporator for simultaneous freshwater production and salt harvesting via edge-preferential crystallization

Solar-driven interfacial evaporation (SDIE) has emerged as a promising technology to alleviate the global freshwater scarcity. However, the simultaneous collection of water and salt as resources while maintaining stable evaporation rate without salt contamination at the evaporation interface remains a huge challenge. Herein, we report a novel mushroom-like cotton-based evaporator, inspired by the vertical stem and inclined caps of mushrooms, for simultaneous freshwater production and salt harvesting. By depositing polyaniline (PANI) and carbon nanotubes (CNTs) onto the cotton fabric (CF), an evaporation rate of 1.88 kg m−2h−1 and a high solar evaporation efficiency of 99.4 % can be achieved in 3.5 wt% NaCl solution under one solar irradiation. Furthermore, a significant water collection efficiency of 70.2 % and a high salt harvesting rate of 42.1 g m−2h−1 can be derived. Even exposed to high-concentration (15 wt%) brine, our design still effectively prevents salt contamination. The distinctive edge-preferential crystallization not only avoids the salt contamination but also promotes the salt harvesting, due to the capillary force, the criss-cross water channels from the nature of cotton cloth, as well as the gravity-assisted water transport of the "mushroom cap" during evaporation. In addition, the low thermal conductivity (0.163 W m−1 K−1) of the photothermal layer with the integration of PANI and CNTs, as well as the vertical water upward transport via the "mushroom stem" effectively reduce the heat loss. This research holds great potential for seawater desalination applications with the comprehensive utilization of seawater resources.