催化作用
化学
均相催化
有机化学
组合化学
同种类的
数学
组合数学
作者
Zhen Zhang,Jian‐Heng Ye,Dongshan Wu,Yuqin Zhou,Da‐Gang Yu
标识
DOI:10.1002/asia.201800672
摘要
Carbon dioxide (CO2 ), a well-known greenhouse gas, is also a nontoxic, readily accessible, and renewable one-carbon (C1) source. However, owing to its thermodynamic stability and kinetic inertness, the efficient utilization of CO2 is challenging. Much effort has been devoted to achieving efficient and selective organic transformations of CO2 . Recently, the synthesis of important oxazolidin-2-ones from unsaturated amines by using CO2 has attracted much attention and been heavily studied. This Focus Review presents recent advances in this area by using homogenous catalysis. The cyclization of amines that contain alkynes, alkenes, and allenes with CO2 is discussed, and possible reaction mechanisms and applications of these transformations are also described.
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