钒
价(化学)
水溶液
离子
无机化学
插层(化学)
锌
电化学
材料科学
光谱学
化学
氧气
物理化学
电极
有机化学
物理
量子力学
作者
Ping Luo,Yao Xiao,Chunli Zuo,Wen Tang,Gangyuan Liu,Shiyu Wang,Wanyue Cai,Shijie Dong,Ping Luo
出处
期刊:Chemsuschem
[Wiley]
日期:2020-12-28
卷期号:14 (3): 971-978
被引量:72
标识
DOI:10.1002/cssc.202002401
摘要
Abstract VO 2 generally has a higher theoretical capacity and layered structure suitable for the intercalation/extraction of zinc ions. However, Zn 2+ ions with high charge density interact with the crystal lattice and limit further improvement in electrochemical performance. Defect engineering is a potential modification method with very promising application prospects, but the established procedures for preparing defects are complicated. In this study, VO 2– x (B) with oxygen deficiency is prepared by a simple solution reaction with NaBH 4 . The presence of oxygen deficiencies is confirmed by positron annihilation lifetime spectroscopy, UV/Vis absorbance spectroscopy and others. Owing to the presence of oxygen defects, the aqueous Zn/VO 2– x (B) battery exhibits improved specific capacity, excellent reversibility, and structural stability. Ex situ characterization techniques are employed to demonstrate the reversible insertion‐extraction mechanism of Zn 2+ ions from and into the host material. In addition, the Zn/VO 2– x (B) batteries still exhibit considerable electrochemical performance, even with high‐loading electrodes (about 4 mg cm −2 ).
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