Adsorption of glyphosate and metabolite aminomethylphosphonic acid (AMPA) from water by polymer-based spherical activated carbon (PBSAC)

Glyphosate (GLY) is the most commonly used herbicide worldwide, and aminomethylphosphonic acid (AMPA) is its main metabolite. Their occurrence in ground and surface waters causes diseases in humans, while complex physico-chemical properties hinder detection and effective removal. Polymer-based spherical activated carbon (PBSAC) can adsorb many micropollutants efficiently and, hence, overcome the shortfalls of conventional treatment methods. The static adsorption of a mixture of GLY and AMPA by PBSAC was investigated with varying PBSAC properties and relevant solution chemistry. The results show that PBSAC can remove 95% GLY and 57% AMPA from an initial concentration of 1 µg/L at pH 8.2. PBSAC properties (size, activation level, and surface charge) have a strong influence on herbicide removal, where surface area plays a key role. Low to neutral pH favors non-charge interactions and results in good adsorption, while higher temperatures equally enhance GLY/AMPA adsorption by PBSAC. The work demonstrated the effective removal of GLY to meet the European guideline concentration (0.1 µg/L), while AMPA could not be removed to the required level.