脱氢
甲酸
甲醇
催化作用
金属间化合物
铂金
过渡金属
蒸汽重整
材料科学
无机化学
金属
电催化剂
燃料电池
质子交换膜燃料电池
化学
化学工程
电化学
合金
物理化学
冶金
制氢
有机化学
电极
工程类
标识
DOI:10.1002/ente.201800553
摘要
Recently, the use of intermetallics as catalysts in various chemical transformations, such as hydrogenation/dehydrogenation, oxidation, and steam reforming, as well as electrocatalysts for oxygen reduction, and their advantages over random alloys in the same composition have been reported. Herein, the effect of atomic ordering on the activity for methanol and formic acid oxidation of low‐temperature fuel cell platinum‐based electrocatalysts is discussed, by comparing ordered and disordered structures with the same Pt/M (in which M is the first and second row transition metal) atomic ratio (3 and 1).
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