分子印迹聚合物
分子印迹
钼
检出限
电化学气体传感器
兴奋剂
材料科学
电化学
选择性
化学
化学工程
分析化学(期刊)
电极
色谱法
催化作用
光电子学
有机化学
物理化学
冶金
工程类
作者
Huan Lu,Jiangxue An,Yan Huang,Hanyue Cui,Jing Yang,Li Li,Yaping Ding
标识
DOI:10.1002/asia.202200453
摘要
A novel molecularly imprinted electrochemical sensor based on nitrogen-doped molybdenum carbide(N-Mo2 C) nanosphere was fabricated for trace analysis of resveratrol in this work. N-Mo2 C with large specific surface area and good electrical conductivity was introduced to construct a sensitive imprinting platform. Molecularly imprinted polymer film was prepared through a simple electropolymerization method using resveratrol as the template molecule and o-phenylenediamine as the functional monomer. The sensor shows great analytical performance in the concentration range of 10-9 mol L-1 to 10-4 mol L-1 and the detection limit is as low as 4.37×10-10 mol L-1 . The sensor also has the advantages of good selectivity, reproducibility and stability, which opens a new way for the application of molecularly imprinted electrochemical sensors in the field ofbiomedicine detection.
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