电解质
电池(电)
二氧化碳
乙烯
锂(药物)
化学
离子
工作(物理)
碳纤维
气相
负二氧化碳排放
溶解度
相(物质)
无机化学
化学工程
材料科学
热力学
有机化学
电极
物理化学
催化作用
固碳
医学
功率(物理)
物理
内分泌学
复合数
工程类
复合材料
作者
Mel Soto,Kae Fink,Christof Zweifel,Peter J. Weddle,Evan Walter Clark Spotte‐Smith,Gabriel M. Veith,Kristin A. Persson,Andrew M. Colclasure,Bertrand J. Tremolet de Villers
标识
DOI:10.1021/acs.jced.3c00692
摘要
During Li-ion battery operation, (electro)chemical side reactions occur within the cell that can promote or degrade performance. These complex reactions produce byproducts in the solid, liquid, and gas phases. Studying byproducts in these three phases can help optimize battery lifetimes. To relate the measured gas-phase byproducts to species dissolved in the liquid-phase, equilibrium proprieties such as the Henry's law constants are required. The present work implements a pressure decay experiment to determine the thermodynamic equilibrium concentrations between the gas and liquid phases for ethylene (C
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