Achieving of High Density/Utilization of Active Groups via Synergic Integration of C=N and C=O Bonds for Ultra-Stable and High-Rate Lithium-Ion Batteries

Organic electrode materials are receiving ever-increasing research interest due to their combined advantages, including resource renewability, low cost, and environmental friendliness. However, their practical applications are still terribly plagued by low conductivity, poor rate capability, solubility in electrolyte, and low density/utilization of active groups. In response, herein, as a proof-of-concept experiment, C=N and C=O bonds are synergically integrated into the backbone of pentacene to finely tune the electronic structures of pentacene. Unexpectedly, the firstly obtained unique 5,7,11,14-tetraaza-6,13-pentacenequinone/reduced graphene oxide (TAPQ/RGO) composite exhibits superior electrochemical performances, including an ultra-stable cycling stability (up to 2400 cycles) and good rate capability (174 mAh g-1 even at a high current density of 3.2 A g-1), which might be attributed to the abundant active groups, π-conjugated molecular structure, leaf-like morphology, and the interaction between TAPQ and graphene.