Switching Electrolyte Interfacial Model to Engineer Solid Electrolyte Interface for Fast Charging and Wide‐Temperature Lithium‐Ion Batteries

-solvent-anion complex is presented to elucidate the differences in SEI formation between ether-based and carbonate-based electrolytes, then interpreting the reason for the obtained higher rate performances. This innovative concept combines the advantages of different electrolytes into one battery system. It is believed that the switching strategy and understanding of the SEI formation mechanism opens a new avenue to design SEI, which is universal for pursuing more versatile battery systems with greater stability.