化学
磷腈
荧光
分子
连接器
微量
镧系元素
猝灭(荧光)
盐酸盐
组合化学
高分子化学
光化学
有机化学
医学
物理
替代医学
病理
量子力学
计算机科学
操作系统
聚合物
离子
作者
Meng Wang,Jinlong Li,Xiao Yu Tang,Qing Lin Guan,Feng‐Ying Bai,Yong‐Heng Xing,Yu Fei Wang
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2023-03-24
卷期号:62 (13): 5145-5157
被引量:8
标识
DOI:10.1021/acs.inorgchem.2c04422
摘要
Hexachlorocyclotriphosphazene is one of the most representative phosphazene compounds which have been proved to have broad application prospects in many fields. However, it is an emerging research perspective to combine cyclotriphosphazene-derived polycarboxylic acid compounds with lanthanides for the construction of Tb-DPCP metal-organic framework (MOF) materials. Herein, a Tb-DPCP MOF, (CH3)2NH2[Tb3(HDPCP)(DMF)(H2O)3]·6DMF (1), was successfully prepared via the reaction of H12HDPCP [hexa(4-carboxyphenoxy) cyclotriphosphazene] and Tb(NO3)3·6H2O under the solvothermal condition. Through fluorescence sensing experiments, it was found that both nitrophenols and chlorophenols could cause the fluorescence quenching of compound 1. At the same time, the compound also exhibited nice trace detection ability for small-molecule drugs (moxifloxacin hydrochloride, balsalazide disodium, and colchicine); the limits of detection were all lower than 0.2 μM. These experimental results fully demonstrated the potential application value of 1 as a multifunctional fluorescent sensor.
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