Supramolecular design and applications of polyphenol-based architecture: A review

聚合物 离子键合 超分子化学 氢键 化学工程 化学 聚合 多酚 纳米技术 涂层 吸附 分子 材料科学 有机化学 离子 抗氧化剂 工程类
作者
Hongshan Liang,Bin Zhou,Di Wu,Jing Li,Bin Li
出处
期刊:Advances in Colloid and Interface Science [Elsevier]
卷期号:272: 102019-102019 被引量:58
标识
DOI:10.1016/j.cis.2019.102019
摘要

Polyphenol-based materials are of wide-spread interest because of the unique properties of the polyphenol itself. Tannic acid, contains high level of galloyl groups, could be coordinated to a range of metal ions to generate robust mental ion-TA films on substrate or even forming hollow capsules. These films or capsules can be used in the field of sensing, separation and catalysis, most importantly in drug/nutraceutical delivery, allowing for the high loading efficiency, high mechanical and thermal stability, pH-responsive disassembly and fluorescence behavior. Additionally, such coating could also provide protection of the sensitive molecules and cells. With the numerous carbonyl and phenolic functional groups, TA has also been demonstrated to form strong hydrogen bonded multilayers with various non-ionic polymers. The properties of the hydrogen-bonded system were highly influenced by the chemical structure of the polymers, which will change the behavior of pH-, temperature- or ionic strength-responsive release of the loading molecules. Additionally, the ionization of galloyl phenol group was attributed to the interaction between TA and other ionic polymers by electrostatic interaction. The electrostatic interaction/hydrogen bonding derived TA/polyme$$%r complexes could deposit on glass slides, microcores or even forming hollow capsules, promising in their applicability to nutraceutical encapsulation, delivery and depot. Notably, polyphenols self-polymerizing could also deposit coatings on different substrates without any exogenous additives, while the comprehensive undertanding about the self-polymerizing mechenism remains unclear. This review provides a promising prospect for utilizing polyphenol-based materials to design versatile architecture in different system, used in the field of chemistry and materials science.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
刚刚
慕青应助Anna采纳,获得10
1秒前
星辰大海应助aaaFAFAFA采纳,获得10
1秒前
2秒前
2秒前
左澄澄完成签到 ,获得积分10
2秒前
3秒前
ONLY完成签到,获得积分10
4秒前
vine发布了新的文献求助10
4秒前
5秒前
2000dw完成签到,获得积分10
5秒前
6秒前
细腻亦巧完成签到,获得积分10
7秒前
orixero应助外向若剑采纳,获得10
7秒前
研友_nEW4G8发布了新的文献求助10
7秒前
桐桐应助江璃采纳,获得10
7秒前
jiao发布了新的文献求助10
7秒前
7秒前
7秒前
8秒前
8秒前
8秒前
8秒前
南浔完成签到,获得积分10
9秒前
lxb应助Cd采纳,获得10
10秒前
带着猫去旅行完成签到,获得积分20
11秒前
11秒前
薛定谔的科研人完成签到,获得积分10
12秒前
小马甲应助一如果一采纳,获得10
12秒前
cc发布了新的文献求助10
12秒前
12秒前
13秒前
13秒前
冷酷亦巧发布了新的文献求助10
13秒前
14秒前
14秒前
开朗满天发布了新的文献求助10
15秒前
酷波er应助活力数据线采纳,获得10
15秒前
15秒前
桐桐应助马小柯采纳,获得10
15秒前
高分求助中
Sustainability in Tides Chemistry 2800
The Young builders of New china : the visit of the delegation of the WFDY to the Chinese People's Republic 1000
Rechtsphilosophie 1000
Bayesian Models of Cognition:Reverse Engineering the Mind 888
Le dégorgement réflexe des Acridiens 800
Defense against predation 800
Very-high-order BVD Schemes Using β-variable THINC Method 568
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3135300
求助须知:如何正确求助?哪些是违规求助? 2786282
关于积分的说明 7776733
捐赠科研通 2442250
什么是DOI,文献DOI怎么找? 1298501
科研通“疑难数据库(出版商)”最低求助积分说明 625124
版权声明 600847