MoSe2@rGO as Highly Efficient Host and Catalyst for Li‐Organosulfide Battery

Organosulfides are promising high-capacity cathode materials for rechargeable lithium batteries. However, sluggish kinetics and inferior utilization impede its practical application in batteries. Rationally designing redox mediators and identifying their active moieties remain formidable challenges. Currently, as a rising star of transition metal dichalcogenides, few-layered MoSe2 decorated reduced graphene oxide (rGO) (MoSe2 @rGO) with high electronic conductivity and narrow energy band is used to manipulate electrocatalytic redox kinetics of organosulfides, thereby enhancing the battery performance. Here, an exotic MoSe2 @rGO is reported with Se defects material obtained from 2D MoSe2 growing on rGO for Li-dipentamethylenethiuram tetrasulfide (Li-PMTT) batteries. MoSe2 @rGO with Se defects has a large specific surface area, and sufficient pores, as well as exce llent catalytic ability for organosulfides conversion reactions. Therefore, the PMTT@MoSe2 @rGO cathode delivers a high reversible capacity of 405 mAh g-1 in the first cycle at 0.5 C and can maintain 238.3 mAh g-1 specific capacity after 300 cycles. This work offers an understanding of organosulfides electrochemistry toward fast and durable performance, holding great promise for developing practically feasible lithium-organosulfides battery material designs.