双环分子
丁烷
螺旋桨烷
戊烷
反应性(心理学)
丙烷
化学
立体化学
有机化学
催化作用
医学
替代医学
病理
作者
Vladimir Ya. Lee,Olga A. Gapurenko
标识
DOI:10.1002/asia.202300903
摘要
In this review, the current state of affairs in the novel field of the group 14 element clusters based on the bicyclo[1.1.0]butane framework, namely, bicyclo[1.1.0]butane, [1.1.1]propellane, and tricyclo[2.1.0.02,5 ]pentane derivatives, are overviewed. Structural similarities and differences between these three classes of highly strained polycyclic compounds are considered from the viewpoint of the critically important nature of their bridgehead bonds. Synthetic strategies towards bicyclo[1.1.0]butanes, [1.1.1]propellanes, and tricyclo[2.1.0.02,5 ]pentanes, as well as their peculiar structural and bonding features, and specific reactivity, are also presented and discussed in this review.
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