热电效应
离子键合
导线
塞贝克系数
材料科学
佩多:嘘
组分(热力学)
离子电导率
离子
电子
导电聚合物
电导率
热电材料
化学物理
电阻率和电导率
热重分析
纳米技术
化学工程
化学
分析化学(期刊)
物理
复合材料
有机化学
工程类
热力学
量子力学
作者
Aung Ko Ko Kyaw,Grayson Dao Hwee Wong,Temesgen Atnafu Yemata,Jianwei Xu
标识
DOI:10.1016/j.orgel.2019.02.014
摘要
By employing time-dependent open-circuit voltage measurement, we demonstrate that a redundant ionic Seebeck component in the mixed ion-electron conducting polymer PEDOT:PSS can be suppressed by simple chemical treatments. The suppression of ionic Seebeck can be attributed to both increase in electronic conductivity and reduction in ionic conductivity, which results in a significant increase in the ratio of electronic-to-ionic conductivity. The thermogravimetric analysis and thickness swelling test confirm that PEDOT:PSS film becomes less or non-hygroscopic after treatment. Low hygroscopicity in the PEDOT:PSS film effectively cuts off the moisture-assisted ion conducting channel, consequently the ionic conductivity becomes extremely low and the ionic Seebeck component is suppressed even at a high humidity (90% RH) condition. The chemical treatment turns out to be a highly promising method to eliminate ionic Seebeck component in the mixed ion-electron conducting polymers and thus to generate consistent thermovoltage for the practical thermoelectric application.
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