硫杂蒽酮
光引发剂
光致聚合物
异佛尔酮二异氰酸酯
双功能
TMPTA公司
光化学
材料科学
聚合
本体聚合
高分子化学
化学
自由基聚合
有机化学
单体
聚合物
聚氨酯
催化作用
作者
Xihong Guo,Haijun Zhou,J.X. Wang
标识
DOI:10.1016/j.porgcoat.2021.106214
摘要
A novel bifunctional photoinitiator (named as TX-EG-IPDI-2959) with thioxanthone and hydroxyalkylphenone moieties was synthesized by the reaction of isophorone diisocyanate with Irgacure 2959 and 2-(2-hydroxyethoxy) thioxanthone. The molecular structure of TX-EG-IPDI-2959 was characterized by 1H NMR, high-resolution mass spectroscopy, UV–vis and FT-IR. The photochemical behavior of TX-EG-IPDI-2959 was investigated through the photolysis and polymerization of butyl acrylate by UV–vis and HRMS. Compared with the combination of Irgacure 2959 and 2-(2-hydroxyethoxy) thioxanthone, the CC bond cleavage of hydroxyalkylphenone to produce free radical fragments was effectively done under the irradiation of visible LED light. The obvious intramolecular synergistic effect between the hydroxyalkylphenone and thioxanthone moieties has been confirmed based on HRMS analysis of photobleach and photopolymerization. In addition, the photopolymerization kinetic of an UV gel and trimethylolpropane triacrylate initiated by TX-EG-IPDI-2959 were also investigated. The plausible photochemical reaction mechanism of TX-EG-IPDI-2959 was proposed.
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