Torrefied herb residues in nitrogen, air and oxygen atmosphere: Thermal decomposition behavior and pyrolytic products characters

The thermal decomposition behavior and pyrolytic products characters of herb residue (HR) torrefied in N2, air and O2 were investigated in present work. The clear gradual regularity of samples in Van Krevelen diagram exhibited the severity and some similarities of torrefaction. The activation energy (E) calculated by distributed activation energy model (DAEM) found that the E values of torrefied samples was higher than raw HR if the conversion is below 0.8. Torrefaction treatment would beneficial to increase the yield of gas but inhibit the formation of oil, and the compounds of gas and bio-oil under different torrefaction conditions are also quite different. It should be noticed that the presence of oxygen in the torrefaction atmosphere would reduce the torrefaction temperature significantly, while maintaining the severity of torrefaction and pyrolytic products distribution.