Pt─O Bond Accelerated Cu0/Cu+ Activity for Boosting Low‐Energy Bipolar Hydrogen Production

Abstract To address the imperative challenge of producing hydrogen in a low‐energy consumption electrocatalytic system, this study emphasizes the utilization of thermodynamically favorable biomass oxidation for achieving energy‐efficient hydrogen generation. This research integrates ultralow PtO 2 ‐loaded flower‐like nanosheets (denoted as PtO 2 @Cu 2 O/Cu FNs) with Cu 0 /Cu + pairs and Pt─O bonds, thereby yielding substantial enhancement in both hydrogen evolution reaction (HER, −0.042 V RHE at 10 mA cm −2 ) and furfural oxidation reaction (FFOR, 0.09 V RHE at 10 mA cm −2 ). As validated by DFT calculations, the dual built‐in electric field (BIEF) is elucidated as the driving force behind the enhanced activities, in which Pt─O bonds expedite the HER, while Cu + /Cu 0 promotes low‐potential FFOR. By coupling the FFOR and HER together, the resulting bipolar‐hydrogen production system requires a low power input (0.5072 kWh per m 3 ) for producing H 2 . The system can generate bipolar hydrogen and high value‐added furoic acid, significantly enhancing hydrogen production efficiency and concurrently mitigating energy consumption.