同质结
光催化
材料科学
氮化物
催化作用
吸附
氧气
光化学
兴奋剂
分解水
碳纤维
石墨氮化碳
X射线光电子能谱
氮化碳
可见光谱
化学工程
纳米技术
化学
光电子学
物理化学
有机化学
图层(电子)
复合材料
工程类
复合数
作者
Ruiyang Zhang,Aili Zhang,Yuehan Cao,Shuyan Wang,Fan Dong,Ying Zhou
标识
DOI:10.1016/j.cej.2020.126028
摘要
Oxygen as an economic and ubiquitous oxidant plays a significant role in catalysis environmental remediation. However, the high thermodynamic stability of O2 limits the practical application. Herein, we reported a novel Mo doped carbon nitride (Mo-CN/g-CN) homojunction via the in-situ growth strategy. The strong interaction between Mo-CN and g-C3N4 enhanced visible-light response and photogenerated electrons and holes pairs separation, which were beneficial for photocatalytic activity. Importantly, theoretical calculation and experiments confirmed that Mo atoms on the surface of Mo-CN/g-CN could provide abundant electrons to the adsorbed O2 to promote the generation of O2−, thus enhancing the photocatalytic performance. Consequently, the obtained Mo-CN/g-CN reveals excellent photocatalytic NO removal activity, demonstrating its promise for air purification. This current work gives a novel insight for O2 activation in the application of photocatalytic environmental remediation.
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