Synthesis and Manipulation of High Aspect Ratio Gold Nanorods Grown Directly on Surfaces

Here we describe the synthesis of Au nanorods directly on glass surfaces using seed-mediated deposition of Au from AuCl4- onto surface-attached 3−5 nm diameter Au nanoparticles (AuNPs) in the presence of cetyltrimethylammonium bromide (CTAB). The average length (200 nm to 1.2 μm) and aspect ratio (6−22) of the nanorods increases with increasing AuCl4- concentration. Short, low aspect ratio Au nanorods are manipulated with an atomic force microscopy (AFM) tip, while longer, high aspect ratio nanorods are bent and broken with the AFM tip.