炭化
膨胀的
聚磷酸铵
聚乳酸
阻燃剂
复合材料
可燃性
材料科学
碳化
复合数
热解
化学工程
聚合物
工程类
扫描电子显微镜
作者
Yaru Sun,Bin Yu,Yan Liu,Fan Bai,Junbo Yan,Wenfang Liu,Fenglei Huang,Shuo Gao
标识
DOI:10.1016/j.coco.2023.101720
摘要
In this work, a special synthetic process of charring-foaming agent nanosheet (2d-CFA) creates soft and smooth tactility, no granule with a soft quality of extension. This well-designed 2d-CFA matches well with ammonium polyphosphate (APP) to form intumescent flame retardant (IFR), obtaining well-pleasing carbonization ability, fire safety, and mechanical properties for polylactic acid (PLA) composite. 2d-CFA can reduce the flammability of the composites by forming a physical barrier against heat and mass transport under early pyrolysis of PLA. Furthermore, heat, CO, and CO2 production in PLA composites are significantly decreased by loading low IFR. The mechanisms of enhanced carbonization ability and fire safety for PLA by loading 2d-CFA/APP are proposed based on gaseous and condensed phase products. This novel and facile modification method provides a new strategy for improving the flame retardant efficiency of IFR.
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