Carbon dots/TiO2 enhanced visible light-assisted photocatalytic of leachate: Simultaneous effects and Mechanism insights

The persistence and potential fouling risks associated with humic substances and bacteria present in leachate have gained increasing attention. Therefore, developing efficient and environmentally compatible technologies for their removal is essential. This study presented the hydrothermal synthesis of a photocatalyst by coupling carbon dots (CDs) and bulk TiO2 (P25). The incorporation of CDs increased the photocatalytic performance by enhancing visible light absorption and facilitating the separation of electrons/holes. Compared to P25, the CDs/P25 exhibited optimal photocatalytic activity for humic acid (HA), fulvic acid (FA), and leachate, with 1.64, 1.02, and 1.12 times higher activity, respectively. Remarkedly, the CDs/P25 accelerated the conversion of large HA molecules into small molecules at a faster rate and higher amount than the bulk P25, due to the increase of hydroxyl radicals, monoclinic oxygen radicals, and superoxide radicals. Additionally, the CDs/P25 demonstrated better bacterial-deactivation ability than the P25, with dead bacteria percentages of 83.3% and 34.6%, respectively. This study provides a promising strategy for efficiently applying CDs/P25 photocatalysis to leachate treatment.