光引发剂
单体
共聚物
高分子
聚合
材料科学
高分子化学
自由基聚合
光致聚合物
化学
化学工程
聚合物
复合材料
生物化学
工程类
作者
Antoine Béziau,Andria Fortney,Liye Fu,Chiaki Nishiura,Haobo Wang,Julia Cuthbert,Eric Gottlieb,Anna C. Balazs,Tomasz Kowalewski,Krzysztof Matyjaszewski
出处
期刊:Polymer
[Elsevier]
日期:2017-09-01
卷期号:126: 224-230
被引量:29
标识
DOI:10.1016/j.polymer.2017.08.035
摘要
The concept of a Structurally Tailored and Engineered Macromolecular gel (STEM gel) is presented. A STEM gel is comprised of a network with latent initiating sites allowing for the post-synthesis, spatially specific modification of the matrix. A direct synthetic method was employed and photo-active STEM gels based on (meth)acrylates were synthesized by free radical copolymerization of different monomers, a crosslinker, and a photo-active dormant initiator/monomer (inimer) based on the radical photoinitiator 2-hydroxy-4′-(2-hydroxyethoxy)-2-methylpropiophenone (Irgacure 2959). Infiltration by a solution of a crosslinker was followed by the UV triggered polymerization of secondary polymeric chains. Irradiation through masks with different transmittance resulted in materials with spatially differentiated mechanical properties.
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