化学
肉眼
RGB颜色模型
荧光
水溶液
比色法
检出限
分析化学(期刊)
有机化学
色谱法
人工智能
光学
计算机科学
物理
作者
Somayeh Tarasi,Ali Ramazani,Ali Morsali,Mao‐Lin Hu
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2021-08-26
卷期号:60 (17): 13588-13595
被引量:8
标识
DOI:10.1021/acs.inorgchem.1c01894
摘要
This study has developed a specific, easy, and novel approach to designing a sacrificial metal–organic framework (MOF) that can detect and measure the amount of Hg2+ in aqueous and nonaqueous solutions using the naked eye. The functionalized [Zn(oba)(RL3)0.5]n·1.5DMF (TMU-59) provides the ability of simple visual assessment or colorimetric readout without sophisticated analytical equipment. Because of the special interaction with Hg2+, degradation of the structure of this unique MOF causes the solution to change color from colorless to a pink that is easily recognizable to the naked eye. The presence of a methyl group plays a major role in naked-eye detection by a qualitative sensor. Furthermore, this qualitative sensor data for the production of a simple, instant, and portable red, green, and blue (RGB)-based quantitative sensor were used to determine the concentration of Hg2+ in different specimens. As a turn-off fluorescence sensor, this unique structure is also capable of detecting Hg2+ at very low concentrations (the limit of detection is 0.16 ppb). To the best of our knowledge, TMU-59 is the first MOF-based naked-eye sensor that can successfully and specifically display the presence of Hg2+ through a major color change.
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