Pulse Radiolysis Studies. XIII. Rate Constants for the Reaction of Hydroxyl Radicals with Aromatic Compounds in Aqueous Solutions

Absolute rate constants have been determined for the reaction of the hydroxyl radical with a variety of aromatic compounds in aqueous solution. The rate constants obtained are significantly higher than values previously reported. Rate constants for the reaction of the hydroxyl radical with methyl alcohol and ethyl alcohol have also been determined by competition kinetics using three of these absolute rate constants as reference values. Comparison of our results with the published values from competition kinetics suggests that the rate constants for the reaction of hydroxyl radicals with iodide ion and thiocyanate ion are significantly higher than reported in earlier work. The ultraviolet absorption bands of the various substituted hydroxycyclohexadienyl radicals formed have been observed.