热释光
高分辨率透射电子显微镜
材料科学
分析化学(期刊)
单斜晶系
傅里叶变换红外光谱
吸热过程
透射电子显微镜
核化学
晶体结构
化学
发光
结晶学
光学
纳米技术
物理化学
光电子学
色谱法
物理
吸附
作者
Mahesh S. Bhadane,S.S. Dahiwale,K.R. Sature,B.J. Patil,V.N. Bhoraskar,S.D. Dhole
标识
DOI:10.1016/j.radmeas.2016.11.009
摘要
A new Dy doped CaNa2(SO4)2 nanophosphor has been synthesized using simple co-precipitation method and claimed to have good Thermoluminescence (TL) dosimetric properties. Structural, morphological, optical, compound identification and thermal analysis of the nanophosphor was studied by X-ray diffraction (XRD), High-Resolution Transmission electron microscope i.e. (HRTEM), UV–Visible, FTIR and TGA-DSC techniques. XRD studies showed a monoclinic structure and size of the particle found to be around ∼45 nm. HRTEM confirms the nanosize of the particles of the same order and SEAD pattern shows fringes perfectly match with inter planner spacing distance “d” of XRD i.e. 2.74 Å. UV–Visible and FTIR analysis revealed the absorption wavelength 246 nm which corresponds to the band gap of around ∼5.03 eV and formation of the compounds of different bonds such as S-O, S=O, SO4 stretch, SS disulfide, respectively. The percentage of weight loss-gain, endothermic changes of the nanophosphor was measured using TGA-DSC analysis and corresponding weight loss of such a nanophosphor with increasing temperature was observed around 12.60%. The TL analysis shows that the CaNa2(SO4)2:Dy has a typical single glow curve at 164 °C and gives excellent linear response curve over a wide range of gamma dose from 10 Gy to 10 kGy. Moreover, the reproducibility of the CaNa2(SO4)2:Dy nanophosphor did not change after numerous cycles of exposures and readouts. Fading has been observed at around 9.55% for 30 days. Theoretical analysis of glow curves of samples irradiated by γ-rays was done by computerized glow curve deconvolution (CGCD) method to find out trapping parameters of various peaks. Finally, CaNa2(SO4)2:Dy nanophosphor could be a potential candidate for applications in the field of accidental and reactor dosimetry.
科研通智能强力驱动
Strongly Powered by AbleSci AI