Mild depolymerization of alkaline lignin in a formic acid-choline chloride type deep eutectic solvent system

Abstract The degradation of lignin can generate a variety of products with diverse applications. Lignin is abundant on earth; however, its high molecular weight and stable properties impede its development. Currently, acid-catalyzed degradation of lignin is a relatively common and promising catalytic method, particularly DES catalytic degradation, which is not only environmentally friendly but also features an excellent degradation effect. This report discusses the degradation mechanism and effect of the formic acid-choline chloride DES system for the degradation of alkaline lignin. According to fourier transform infrared spectroscopy (FTIR) and 1 H-NMR spectroscopy, it is evident that the phenolic hydroxyl content of lignin increases after degradation, which indicates the cleavage of β - O -4′ ether bonds in the macromolecular structure. Gel permeation chromatography (GPC) was employed to determine the molecular weight of degraded lignin, and regenerated lignin with low molecular weight and low dispersibility was obtained. The minimum average molecular weight ( M w ) was 2.3 × 10 3 g/mol. During the depolymerization process, it was also discovered that the repolymerization and degradation reactions formed a competitive relationship. The lignin oil contained primarily propanoic acid ethyl ester, acetic acid butyl ester, 2-methoxy-4-propyl phenol, 2-methoxy phenol, and apocynin, as determined by GC-MS.