催化作用
光催化
饮用水净化
化学工程
传质
水处理
化学
同种类的
降级(电信)
污染物
人体净化
碳纤维
分解
材料科学
环境化学
环境工程
色谱法
废物管理
环境科学
有机化学
电信
物理
复合数
计算机科学
工程类
复合材料
热力学
作者
Zhenxing Zeng,Long Tan,Fei Ye,Munir Ahmad,Xiaojing Wang,Dexin Fang,P. Hong,Shihuai Deng,Hong Xiao
标识
DOI:10.1016/j.apsusc.2024.159352
摘要
Heterogeneous catalysis has been considered a promising way for waste purification, however the catalytic performances of the heterogeneous-based systems are still unsatisfactory, mainly due to the limited active sites exposure and sluggish reactants mass transfer. In this study, we propose a conceptual carbonitride-based quasi-homogeneous catalytic system, exhibiting remarkable photocatalytic activity toward organic pollutants degradation and pathogenic bacteria inactivation. We verify that downsizing carbonitride into nanodot level and modifying the material with hydrophilic groups can endow it with water soluble ability, forming a quasi-homogeneous catalytic system to maximize the active sites exposure and minimize the reactants mass transfer resistance for high-efficient water purification. As a result, the as-established quasi-homogeneous photocatalytic system exhibits abundant surface-active sites and reactants mass transfer efficiencies that allows remarkable O2 reduction for ROS generation. In addition, the treated water containing the functionalized carbonitride is found capable of driving the fast flocculate of suspended substance, which helps to build a well water decontamination and suspended substance removal water purification nexus for practical applications. The work demonstrated here sheds new light in designing high-efficient homogeneous catalytic system for energy and environmental related applications.
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