Advances of Zn Metal‐Free “Rocking‐Chair”‐Type Zinc Ion Batteries: Recent Developments and Future Perspectives

Abstract Aqueous zinc ion battery (AZIBs) has attracted the attention of many researchers because of its safety, economy, environmental protection, and high ionic conductivity of electrolytes. However, the battery greatly suffers from zinc dendrite produced by zinc metal anode leading to poor cycle life and even unsafe problems, which limit its further development for various important applications. It is known that the success of the commercialization of lithium‐ion batteries (LIBs) is mainly due to replacement of lithium metal anode with graphite, which avoids the formation of Li dendrite. Therefore, it is an important step to develop aqueous zinc ion anode to replace conventional zinc metal one with zinc‐metal free anode material. In this review, the working principle and development prospect of “rocking‐chair” AZIBs are introduced. The research progress of different types of zinc metal‐free anode materials and cathode materials in “rocking‐chair” AZIBs is reviewed. Finally, the limitations and challenges of the Zn metal‐free “rocking‐chair” AZIBs as well as solutions are deeply discussed, aiming to provide new strategies for the development of advanced zinc‐ion batteries.