三苯基氧化膦
三苯基膦
甲苯
大小排阻色谱法
卤化物
降水
过滤(数学)
化学
溶剂
氧化物
高分子化学
有机化学
催化作用
气象学
物理
统计
数学
酶
标识
DOI:10.1021/acs.oprd.2c00104
摘要
A reliable and scalable purification procedure for the easy removal of triphenylphosphine oxide by complexation with CaBr2 in ethereal solvents or toluene was developed. The resulting insoluble precipitated complex was easily eliminated from crude reaction mixtures in high yields by filtration without the need of purification by column chromatography. The compatibility of this procedure with different organic solvents, salts, filtration aids, packing materials, and several molecules containing most common organic functional groups was examined to explore the scope and limitations of this method. Additionally, precipitation of TPPO by complexation with other halide salts was also explored.
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