材料科学
电极
芯(光纤)
辅助电极
碳纤维
壳体(结构)
薄膜
薄膜太阳能电池
光电子学
太阳能电池
化学工程
纳米技术
复合材料
物理化学
化学
复合数
工程类
电解质
作者
Xiaoyu Zhang,Shusen Yang,Ying Cao,Chengyang Liang,Shitong Geng,Haipeng Guo,Ying Liu,Yanhong Luo,Wenming Zhang,Ling Li
标识
DOI:10.1016/j.surfin.2022.102374
摘要
In this paper, NiFe 2 O 4 nanoparticles coated with CuCo 2 O 4 linear core-shell structure crystals were grown in situ using carbon paper (CP) as support material by two-step hydrothermal method . The composite materials of CuCo 2 O 4 @NiFe 2 O 4 /CP are coated on a titanium mesh base to make the counter electrodes (CEs) of the dye-sensitized solar cells (DSSCs). The photovoltaic conversion efficiency (PCE) of the CuCo 2 O 4 @NiFe 2 O 4 /CP CEs is 10.00%, which is much higher than the representative Pt CEs (7.74%). Its excellent electrochemical performance can be put down to the core-shell structure with high porosity and specific surface area, which can provide abundant active sites for redox reactions in the electrolyte, and a large number of transition metal elements greatly enhance the catalytic ability of the electrode. In addition, the resistance between the electrode material and the substrate is greatly reduced by using titanium mesh as the substrate. This study provides a new idea and possibility for the development of high efficiency and platinum-free CEs materials and a new conductive substrate is developed to improve the photoelectric performance of the CEs.
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