Interfacial and molecular interactions between fractions of heavy oil and surfactants in porous media: Comprehensive review

The oil production by the natural energy in oil reservoirs is decreasing gradually. Only 25–30% of the world's reservoirs can be produced naturally, and different methods are employed to recover the remaining oil. The use of surfactants is one of the promising methods for unlocking the residual oil after natural depletion. In such a method, one of the main challenges is to study how surfactant, oil, and water interact and how porous media affect these interactions. Molecular dynamics (MD) simulation provides an opportunity to gain insights into this challenge. MD simulation can be used to study interactions between surfactant, oil, and water statically and dynamically in porous media. This paper presents a comprehensive review of interactions between surfactants and fractions of oil/heavy oil, including asphaltene, resin, aromatics, and saturates. Also, it explains the probable mechanisms of oil detachment from reservoir rock in the presence of surfactants. A thorough grasp of molecular interactions between surface-active agents and different fractions of oil helps us to develop successful surfactant-based oil recovery methods.