材料科学
热电效应
碳纳米管
热电发电机
载流子
塞贝克系数
超晶格
极性(国际关系)
热电材料
复合材料
能量转换效率
苯酚
极性反转
热导率
光电子学
电压
有机化学
电气工程
细胞
物理
化学
工程类
热力学
生物
遗传学
作者
Kuncai Li,Liqing Xu,Zhanchao Li,Yizhuo Wang,Jing Wang,Qi Xia,Qing Li,Hong Wang
出处
期刊:Nano Energy
[Elsevier]
日期:2021-02-21
卷期号:84: 105902-105902
被引量:29
标识
DOI:10.1016/j.nanoen.2021.105902
摘要
Solar energy conversion is of great interest in developing green and sustainable energy. Herein, we report the solar-to-electricity capability of a new two dimensional (2D) Cu2S-phenol superlattice (CP-SL) and carbon nanotubes (CNTs) composites for the first time. CP-SL is demonstrated to have a high Seebeck coefficient and a low thermal conductivity comparable to that of metal-organic frameworks. CP-SL based solar thermoelectric generator (STEG) exhibits stable output voltages for long time usages superior to previously reported STEGs. The device is made of p- and n-type modules that are composed of CP-SL/CNT and CP-SL/polyethyleneimine (PEI) doped CNTs (PEI-CNT) composites, respectively. The polarity of the composites is dominated by the CNTs which have higher carrier concentration. The carrier transport mechanism in the composites matches well with a parallel model, indicating the CP-SL and CNT interfaces play a minor role in carrier transport. The maximum ZT value of CP-SL/CNT is achieved by an in-situ growth method, which is about 35 times higher than that of the original CP-SL. These results indicate that 2D CP-SL is a new material with tunable thermoelectric properties and polarities, which may lay a foundation to realize p- and n-type properties in one material for single-material organic electronic devices development.
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