Tough and Highly Efficient Underwater Self‐Repairing Hydrogels for Soft Electronics

The vulnerability of hydrogel electronic materials to mechanical damage due to their soft nature has necessitated the development of self-repairing hydrogel electronics. However, the development of such material with underwater self-repairing capability as well as excellent mechanical properties for application in aquatic environments is highly challenging and has not yet been fully realized. This study designs a tough and highly efficient underwater self-repairing supramolecular hydrogel by synergistically combining weak hydrogen bonds (H-bonds) and strong dipole-dipole interactions. The resultant hydrogel has high stretchability (up to 700%) and toughness (4.45 MJ m-3 ), and an almost 100% fast strain self-recovery (10 min). The underwater healing process is rapid and autonomous (98% self-repair efficiency after 1 h of healing). Supramolecular hydrogels can be developed as soft electronic sensors for physiological signal detection (gestures, breathing, microexpression, and vocalization) and real-time underwater communication (Morse code). Importantly, the hydrogel sensor can function underwater after mechanical damage because of its highly efficient underwater self-repairing capability.