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Advanced Energy MaterialsVolume 10, Issue 4 2070017 Back CoverFree Access Lithium Batteries: Unraveling the Intra and Intercycle Interfacial Evolution of Li6PS5Cl-Based All-Solid-State Lithium Batteries (Adv. Energy Mater. 4/2020) Jun Zhang, Jun Zhang College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorChao Zheng, Chao Zheng College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorLujie Li, Lujie Li College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorYang Xia, Yang Xia College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorHui Huang, Hui Huang College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorYongping Gan, Yongping Gan College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorChu Liang, Chu Liang College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorXinping He, Xinping He College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorXinyong Tao, Xinyong Tao College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorWenkui Zhang, Wenkui Zhang College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this author Jun Zhang, Jun Zhang College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorChao Zheng, Chao Zheng College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorLujie Li, Lujie Li College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorYang Xia, Yang Xia College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorHui Huang, Hui Huang College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorYongping Gan, Yongping Gan College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorChu Liang, Chu Liang College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorXinping He, Xinping He College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorXinyong Tao, Xinyong Tao College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this authorWenkui Zhang, Wenkui Zhang College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014 P. R. ChinaSearch for more papers by this author First published: 28 January 2020 https://doi.org/10.1002/aenm.202070017Citations: 7AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract In article number 1903311, Wenkui Zhang and co-workers perform in situ and ex situ measurements to monitor the interfacial evolutions in an all-solid-state LiNi0.8Co0.1Mn0.1O2/Li6PS5Cl/Li battery. The interfacial evolutions (changes of space charge layer and chemical bond vibration) are very different inter- and intracycle. Li+ ion migration has a significant influence on these interfacial behaviors. Citing Literature Volume10, Issue4January 28, 20202070017 RelatedInformation