Exploring the mechanism of norfloxacin removal and active species evolution by coupling persulfate activation with biochar hybridized Fe3O4 composites

In situ growth of dispersed active sites on substrates is a strategy for designing highly efficient catalysts for sulfate radical (SO4•-)-based advanced oxidation processes (SR-AOPs). Here, magnetic biochar composite (Fe3O4/BC) was fabricated as an activator to trigger PDS (peroxydisulfate) for norfloxacin (NOR) removal, achieving reliable NOR removal efficiency (>90%) within 10 min. Based on the synergistic effect between Fe3O4 and BC, the removal rate increases to 0.0265 L mg-1 min-1. Fe3O4/BC exhibited decent adaptability, stability, and recyclability toward affecting factors variation during PDS activation, attributed to the synergistic effect between Fe3O4 and BC. The electron transfer of magnetic Fe3O4 coupled with the adsorption and conduction function of carbon skeleton, which overcomes typical problems as crystal agglomeration, metal leaching, and catalysts recovery etc. The electron-rich Fe(II) sites promote the radical pathway by generating reactive oxygen species (ROS, •OH, SO4•- and O2•-), and radicals evolution contributing to the form of 1O2 in non-radical pathway. Under the effect of multipath in NOR degradation, HPLC-QTOF-MS spectroscopy and DFT calculation revealed the possible degradation pathway of NOR. In addition, according to toxicity prediction, the overall NOR contamination toxicity of NOR was effectively alleviated by Fe3O4/BC + PDS system. Overall, this study presents a promising composite in PDS activation and views the active species evolution in the NOR removal system, which is crucial for mechanism study in relevant research in the future.