Preparation and Properties of Pyrotechnic Binder Encapsulated α‐AlH3 Composites by Solvent/Anti‐solvent Method

Abstract Alpha‐aluminum hydride (α‐AlH 3 ) is an ideal energetic combustion agent, but its poor stability and safety limit its application. Therefore, we prepare different composites by using the solvent/anti‐solvent method to coat different pyrotechnic binders on the surface of α‐AlH 3 . The vacuum stability test show that the minimum outgassing of Shellac‐coated α‐AlH 3 composite is only 1.2 mL/g at 50 °C for 6 days. Due to the good electrical insulation properties of Viton, Viton‐coated α‐AlH 3 composite have the highest E 50 value of electrostatic sensitivity. In addition, the pyrotechnic binders coating not only protects the activity of the α‐AlH 3 but also effectively increases its burning rate. Viton‐coated α‐AlH 3 composite have more gaseous products and maximum flame area during combustion. This study illustrates that α‐AlH 3 coated with pyrotechnic binders is a means to address its stability and safety, laying the foundation for its application in solid propellants.