材料科学
Boosting(机器学习)
多硫化物
化学工程
硫黄
纳米花
锂(药物)
Crystal(编程语言)
电极
纳米技术
电解质
冶金
物理化学
化学
纳米结构
机器学习
医学
工程类
计算机科学
程序设计语言
内分泌学
作者
Ruixian Duan,Xifei Li,Guiqiang Cao,Liping Chen,Jun Li,Qinting Jiang,Yanyan Cao,Jingjing Wang,Wenbin Li
出处
期刊:Nanotechnology
[IOP Publishing]
日期:2022-12-30
卷期号:34 (15): 155401-155401
被引量:2
标识
DOI:10.1088/1361-6528/acaf35
摘要
The battery performance of sulfur cathode has obviously depended on the redox reaction kinetics of polysulfides upon cycling. Herein, an effective strategy was proposed to achieve the conversion from 2H (semiconductor phase) to 1T (metal phase) in hollow nano-flowered molybdenum selenide sphere (HFSMS) through crystal phase engineering. The HFSMS with different phase ratio was realized by regulating the proportion of reducing agents. Specifically, the 1T phase content can reach up to 60.8%, and then subsequently decreased to 59.1% with the further increase of the reducing agent. The as-prepared HFSMS with the 1T phase content of 60.8% showed a smallest Tafel slopes (49.99 and 79.65 mV/dec in reduction and oxidation process, respectively), fastest response time and highest response current (520 s, 0.459 mA in Li2S deposition test), which further exhibited excellent catalytic activity and faster reaction kinetics. This result was verified by electrochemical performance, which manifested as stable cycle life with only 0.112% capacity decay per cycle. It was found that the hollow structure can ensures a rich sulfur storage space, and effectually buffer the volume changes of the active substance. More importantly, the improved performance is attributed to the introduction of the 1T phase, which significantly improves the catalytic activity of MoSe2with promoting the polysulfide conversion.
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