Spectroscopic Evidence for the Structure Directing Role of the Solvent in the Synthesis of Two Iron Carboxylates

Angewandte Chemie International EditionVolume 51, Issue 50 p. 12490-12494 Communication Spectroscopic Evidence for the Structure Directing Role of the Solvent in the Synthesis of Two Iron Carboxylates† Tadeja Birsa Čelič, Tadeja Birsa Čelič Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia) Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)Search for more papers by this authorDr. Mojca Rangus, Dr. Mojca Rangus Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia) Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)Search for more papers by this authorDr. Károly Lázár, Dr. Károly Lázár Centre for Energy Research, Institute of Isotopes, HAS, P.O. Box 77, 1525 Budapest (Hungary)Search for more papers by this authorProf. Venčeslav Kaučič, Prof. Venčeslav Kaučič Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia) Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)Search for more papers by this authorProf. Nataša Zabukovec Logar, Corresponding Author Prof. Nataša Zabukovec Logar natasa.zabukovec@ki.si Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia) Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia)Search for more papers by this author Tadeja Birsa Čelič, Tadeja Birsa Čelič Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia) Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)Search for more papers by this authorDr. Mojca Rangus, Dr. Mojca Rangus Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia) Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)Search for more papers by this authorDr. Károly Lázár, Dr. Károly Lázár Centre for Energy Research, Institute of Isotopes, HAS, P.O. Box 77, 1525 Budapest (Hungary)Search for more papers by this authorProf. Venčeslav Kaučič, Prof. Venčeslav Kaučič Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia) Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)Search for more papers by this authorProf. Nataša Zabukovec Logar, Corresponding Author Prof. Nataša Zabukovec Logar natasa.zabukovec@ki.si Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia) Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia)Search for more papers by this author First published: 13 November 2012 https://doi.org/10.1002/anie.201204573Citations: 25 † This work was supported by the Slovenian Research Agency research programme P1-0021, Sloveninan-Hungarian bilateral project TÉT_10-1-2011-0624, DESY, and the EU FP7/2007-2013 programme ELISA (grant number 226716). Access to SR facilities of ELETTRA (project number 20105073) and HASYLAB (project II-20080058 EC), and collaboration with Prof. Iztok Arčon is acknowledged. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Crystal engineering: The synthesis of the known compounds MIL-100(Fe) and MIL-45(Fe) is characterized by spectroscopy. The products are obtained under identical conditions by varying the solvent from pure water to a mixture of water and acetone. The starting solution, the gel, and the final reaction product were characterized by X-ray absorption spectroscopy (see picture). Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201204573_sm_miscellaneous_information.pdf1.5 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue50December 7, 2012Pages 12490-12494 RelatedInformation