氧化物
材料科学
内氧化
合金
图层(电子)
腐蚀
高温腐蚀
熔点
复合材料
基质(化学分析)
亚稳态
冶金
化学
有机化学
作者
Lidong Xing,Chao Gu,Ziyu Lv,Yanping Bao
标识
DOI:10.1016/j.corsci.2021.110076
摘要
The oxidation behavior and mechanism near the crack of bloom was investigated by prefabricated crack and oxidation at high temperature (1000 – 1200 °C). The interface oxide layer composed of Fe2SiO4 and FeCr2O4 can prevent the steel matrix from being oxidized. However, the melting point of Fe2SiO4 is approximately 1170 °C, so the interface oxide layer is in a metastable state with the progress of high-temperature oxidation. At this time, the thickness of the internal oxidation spot layer in the steel matrix increases rapidly. As a result, internal oxidation mechanism of surface cracks at high temperature is clarified.
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