光催化
化学
异质结
制氢
肖特基势垒
电子转移
催化作用
复合数
氢
光化学
纳米技术
化学工程
光电子学
材料科学
复合材料
有机化学
工程类
二极管
作者
Wei Yan,Yangyang Xu,Shengwei Hao,Zhengdong He,Lele Wang,Qingyuan Wei,Jing Xu,Hua Tang
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2022-03-09
卷期号:61 (11): 4725-4734
被引量:52
标识
DOI:10.1021/acs.inorgchem.2c00045
摘要
A reasonable design of samples with efficient spatial separation for photoinduced electron-hole pairs toward the photocatalytic hydrogen evolution reaction (HER) has gained significant attention. Herein, a new C/MoS2@ZnIn2S4/Co3O4 composite with a core-shell structure is designed toward photocatalytic hydrogen production on C/MoS2 and Co3O4 dual electron collectors. Co3O4 nanoparticles as the co-catalyst would form a Schottky junction with ZnIn2S4 nanosheets while the C/MoS2 hollow core would form the step-scheme (S-scheme) heterojunction with ZnIn2S4 sheets, which provides a dual photogenerated electron transfer pathway during the light irradiation process. In addition, the unique core-shell architecture offers large contact interfaces favoring the exposure of rich active sites, which facilitated the separation and the transfer of charges. Consequently, all these factors endowed the C/MoS2@ZnIn2S4/Co3O4 composite with enhanced light absorption ability and an increased hydrogen evolution rate of 6.7 mmol·g-1·h-1 under 420 nm light irradiation, which is about 23.4- and 4.5-fold that of ZnIn2S4 and CMZ, respectively. This work offers a guideline for designing efficient composite photocatalysts toward the photocatalytic HER.
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