气凝胶
材料科学
纳米流体
离子
纳米技术
化学工程
复合材料
纳米颗粒
有机化学
工程类
化学
作者
Feng Zhang,Jianyong Yu,Yang Si,Bin Ding
标识
DOI:10.1002/adma.202302511
摘要
Abstract Osmotic power, also known as “blue energy”, is a vast, sustainable, and clean energy source that can be directly converted into electricity by nanofluidic membranes. However, the key technological bottleneck for large‐scale osmotic electricity is that macroscopic‐scale bulky membrane cannot synergistically satisfy the demands of high power density and low resistance without sacrificing scalability and mechanical robustness. Here, inspired by the anatomy and working principle of electric eels, which harness osmotic energy through embedded neuron‐mediated fibril nanochannels with nanoconfined transport dynamics. Fibrous nanofluidic meta‐aerogel ion motors, 3D‐assembled from nanofluidic cable fibers with actuatable stimulation/transport “ion highways” are engineered. The meta‐aerogel exhibits the integrated coupling effect of boosted ion propulsion and surface‐charge‐dominated selective ion transport. Driven by osmosis, the meta‐aerogel ion motor can produce an unprecedented output power density of up to 30.7 W m −2 under a 50‐fold salinity gradient. Advancing ultra‐selective ion transport in nanofluidic meta‐aerogels may provide a promising roadmap for blue energy harvesting.
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